Qualitative Analysis of Organic Compounds

IMPORTANT

Qualitative Analysis of Organic Compounds: Overview

This topic covers concepts such as Qualitative Analysis of Organic Compounds, Detection of Carbon and Hydrogen, Process for Detection of Carbon and Hydrogen, Lassaigne's Test, Detection of Nitrogen, Detection of Sulphur, Detection of Phosphorus, etc.

Important Questions on Qualitative Analysis of Organic Compounds

MEDIUM
IMPORTANT

The compound formed in the positive test for nitrogen with the Lassaigne's solution of an organic compound is

HARD
IMPORTANT

Compound XC3H6O gives negative tests with the following reagents.

(a) Br2 

(b) 2,4-Dinitrophenylhydrazine

(c) Na metal.

It gives two monochloro structural isomers.

Identify 'X'.

EASY
IMPORTANT

What is the colour of the ammonium phosphomolybdate precipitate which is formed during the detection of phosphorus?

EASY
IMPORTANT

For the detection of phosphorus, the organic compound after fusion with Na2O2 is extracted with water, boiled with HNO3 and then ammonium molybdate added to it. A yellow precipitate is obtained which is due to formation of:

HARD
IMPORTANT

The acid used in the detection of phosphorus in an organic compound is : 

EASY
IMPORTANT

In the detection of carbon and hydrogen(Qualitative analysis of organic compounds), Hydrogen is oxidised to water(tested with anhydrous copper sulphate, which turns_____).

EASY
IMPORTANT

What is the colour of the precipitate we can observe in the reaction between chloride ion with AgNO3 solution ?

EASY
IMPORTANT

In Lassaigne sodium fusion test, N and S of an organic compound are converted into ________

HARD
IMPORTANT

Detection of sulphur in Lassaigne's test is not done by which of the following reagents?

HARD
IMPORTANT

Which reagent is used for the detection of sulphur?

EASY
IMPORTANT

Which of the following is the chemical formula of ammonium phosphomolybdate ?

EASY
IMPORTANT

An organic compound on heating with CuO produces CO2 but not water. The organic compound may be

MEDIUM
IMPORTANT

The Lassaigne's solution when heated with ferrous sulphate and acidified with sulphuric acid gives an intense blue colour indicating the presence of nitrogen. The blue colour is due to the formation of

HARD
IMPORTANT

Which of the following tests can be used to distinguish between methanol and ethanol.

HARD
IMPORTANT

Which of the following gives red colour in Victor Meyer's test?

HARD
IMPORTANT

The oxidation states of the iron atoms in prussain blue coloured complex formed during the test for the presence of nitrogen in an organic compound are

EASY
IMPORTANT

Sodium nitroprusside reacts with sulphide ion to give a purple colour due to the formation of

EASY
IMPORTANT

Among the following statements, select the correct statement regarding the preparation of Lassaigne's extract of a given organic compound.

HARD
IMPORTANT

The sodium extract is boiled with a few drop of nitric acid with compounds X and Y during the test of halogen by silver nitrate .Identify the compound X and Y .

 

EASY
IMPORTANT

During the test for halogens, when Lassaigne's extract is boiled with concentrated HNO3, it: